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Effects of support acidity on the reaction mechanisms of selective catalytic reduction of NO by CH

Shicheng XU, Junhua LI, Dong YANG, Jiming HAO

《环境科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 186-193 doi: 10.1007/s11783-009-0016-5

摘要： The reaction mechanisms of selective catalytic reduction (SCR) of nitric oxide (NO) by methane (CH ) over solid superacid-based catalysts were proposed and testified by DRIFTS studies on transient reaction as well as by kinetic models. Catalysts derived from different supports would lead to different reaction pathways, and the acidity of solid superacid played an important role in determining the reaction mechanisms and the catalytic activities. Higher ratios of Br?nsted acid sites to Lewis acid sites would lead to stronger oxidation of methane and then could facilitate the step of methane activation. Strong Br?nsted acid sites would not necessarily lead to better catalytic performance, however, since the active surface NO species and the corresponding reaction routes were determined by the overall acidity strength of the support. The reaction routes where NO moiety was engaged as an important intermediate involved moderate oxidation of methane, the rate of which could determine the overall activity. The reaction involving NO moiety was likely to be determined by the step of reduction of NO. Therefore, to enhance the SCR activity of solid superacid catalysts, reactions between appropriate couples of active NO species and activated hydrocarbon intermediates should be realized by modification of the support acidity.

关键词： selective catalytic reduction (SCR)     nitric oxide (NO)     methane     support acidity     Br?nsted acid sites     NOy species    

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Conversion of polyethylene to gasoline: Influence of porosity and acidity of zeolites

《能源前沿（英文）》   页码 763-774 doi: 10.1007/s11708-023-0897-1

摘要： Plastic waste is causing serious environmental problems. Developing efficient, cheap and stable catalytic routes to convert plastic waste into valuable products is of great importance for sustainable development, but remains to be a challenging task. Zeolites are cheap and stable, but they are usually not efficient for plastic conversion at a low temperature. Herein a series of microporous and mesoporous zeolites were used to study the influence of porosity and acidity of zeolite on catalytic activity for plastics conversion. It was observed that H-Beta zeolite was an efficient catalyst for cracking high-density polyethylene to gasoline at 240 °C, and the products were almost C4–C12 alkanes. The effect of porosity and acidity on catalytic performance of zeolites was evaluated, which clearly visualized the good performance of H-Beta due to high surface area, large channel system, large amount accessible acidic sites. This study provides very useful information for designing zeolites for efficient conversion of plastics.

关键词： plastics conversion     polyethylene     zeolites     acidity     porosity    

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Precise regulation of acid pretreatment for red mud SCR catalyst: Targeting on optimizing the acidity

《环境科学与工程前沿（英文）》 2022年 第16卷 第7期 doi: 10.1007/s11783-021-1447-x

摘要：

• The optimum SCR activity was realized by tuning the acid pretreatment.

关键词： Air pollution control     Nitrogen oxides     Selective catalytic reduction     Red mud     Solid waste utilization    

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Enhanced CuCl dispersion by regulating acidity of MCM-41 for catalytic oxycarbonylation of ethanol to

Pengzhen CHEN, Shouying HUANG, Jijie ZHANG, Shengping WANG, Xinbin MA

《化学科学与工程前沿（英文）》 2015年 第9卷 第2期   页码 224-231 doi: 10.1007/s11705-014-1447-5

摘要： CuCl supported on molecular sieves has attracted increasing attention in catalyzing oxidative carbonylation of ethanol to diethyl carbonate. Mesoporous MCM-41 has been widely used as catalyst support due to its large surface area and well defined mesoporous structure. Considering its intrinsic weak acidity, MCM-41 was modified by a simple impregnation method to incorporate Al. The incorporation of Al components resulted in the high dispersion of Cu species and the increase of acid sites without changing the mesoporous structure of MCM-41, and thus enhanceed the catalytic activity of CuCl/MCM-41for diethyl carbonate synthesis.

关键词： MCM-41     acidity     oxidative carbonylation     diethyl carbonate    

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Reductive amination of -hexanol to -hexylamine over Ni–Ce/-AlO catalysts

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 82-92 doi: 10.1007/s11705-022-2181-z

摘要： The amination of alkyl alcohols is one of the most promising paths in synthesis of aliphatic amines. Herein, cerium doped nickel-based catalysts were synthesized and tested in a gas-phase amination of n-hexanol to n-hexylamine. It was found that the activity of the Ni/γ-Al2O3 catalyst is significantly improved by doping an appropriate amount of cerium. The presence of cerium effectively inhibits the agglomeration of nickel particle, resulting in better Ni dispersion. As Ni particle size plays critical role on the catalytic activity, higher turnover frequency of n-hexanol amination was achieved. Cerium doping also improves the reduction ability of nickel and enhances the interactions between Ni and the catalyst support. More weak acid sites were also found in those cerium doped catalysts, which promote another key step—ammonia dissociative adsorption in this reaction system. The overall synergy of Ni nanoparticles and acid sites of this Ni–Ce/γ-Al2O3 catalyst boosts its superior catalytic performance in the amination of n-hexanol.

关键词： amination     alcohol     cerium     nickel     acidity     interaction    

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Vanadium(IV) solvent extraction enhancement in high acidity using di-(2-ethylhexyl)phosphoric acid with

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 56-67 doi: 10.1007/s11705-022-2185-8

摘要： Separation of vanadium from black shale leaching solution at low pH is very meaningful, which can effectively avoid the generation of alkali neutralization slag and the resulting vanadium loss. In this study, coordination mechanism of vanadium in acid leaching solution at low pH was investigated with the intervention of chloride ions. Under the conditions of pH 0.8, di-(2-ethylhexyl)phosphoric acid concentration of 20%, phase ratio of 1:2, and extraction time of 8 min, the vanadium extraction could reach 80.00%. The Fourier transform infrared and electrospray ionization results reveal that, despite the fact that the chloride ion in the leachate could significantly promote vanadium extraction, the chloride ion does not enter the organic phase, indicating an intriguing phenomenon. Among Cl−–V, SO42−–V, and H2O–V, the V–Cl bond is longer and the potential difference between coordinate ions and vanadium is smaller. Therefore, VO2+ gets easily desorbed with chloride ions and enter the organic phase. At the same time, the hydrogen ions of di-(2-ethylhexyl)phosphoric acid also enter the water phase more easily, which reduces the pH required for the extraction reaction.

关键词： vanadium     black shale     solvent extraction     high acidity extraction    

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舰船综合保障系统设计

祝 泓,张 平

《中国工程科学》 2015年 第17卷 第5期   页码 44-50

摘要：

本文在分析国外综合保障系统的基础上，提出了适用于我国舰船的保障系统顶层设计方案，给出了系统组成、主要功能和主要技术指标，将综合保障系统划分为保障资源系统、装备综合保障管理信息系统、装备故障诊断与健康管理系统三个分系统，并对各分系统的系统功能和组成进行了阐述，为舰船装备开展综合保障系统集成和管理提供了参考。

关键词： 舰船     综合保障系统     系统设计     保障资源    

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Socialized care services for the aged population: System construction and support measures

《工程管理前沿（英文）》 2023年 第10卷 第2期   页码 339-353 doi: 10.1007/s42524-022-0208-2

摘要： Given the aging society, an increase in social demand, information- and communication technology-driven culture, and government policy support emerges to enable the development of the socialized care services system for the aged (SCSSA). The development of the SCSSA would be a significant step toward addressing China’s aging population. However, the construction of the SCSSA challenges the theories and methods of traditional elderly care service system construction. Specifically, the implementation path for such elderly care service policies is unclear, the necessary technological support is insufficient, and the mechanism for integrating intelligent information technology remains underexplored. Thus, this paper focuses on the needs of the elderly, grounded in the context of the changing elderly care service policies in China, and proposes a research paradigm that integrates system construction and support measure embedding. We then construct the original SCSSA, which includes “material + spirit + medical treatment + healthcare” and propose a method of optimization and iteration. Finally, we build the research framework of systematic support measures from the perspectives of policy reconstruction, institutional embeddedness, and technical support. Our work provides theoretical support and practical guidance for the construction and dynamic optimization of the SCSSA, thus making a significant contribution that will help China effectively cope with its aging society.

关键词： socialized     care service for the elderly     system construction     support measure    

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BMP decision support system for evaluating stormwater management alternatives

Mow-Soung CHENG, Jenny X. ZHEN, Leslie SHOEMAKER,

《环境科学与工程前沿（英文）》 2009年 第3卷 第4期   页码 453-463 doi: 10.1007/s11783-009-0153-x

摘要： Prince George’s County, Maryland, in the Washington D.C. metropolitan area has developed a best management practice decision support system (BMPDSS) to support analysis and decision making for stormwater management planning and design at both the site scale and the watershed levels. This paper presents a detailed description of the BMPDSS. A case study that demonstrates the application of the system is also included. The case study involves a Green Highway project located in a highly urbanized area within the Anacostia River watershed of the county. Several best management practices (BMP) such as bioretention, filter vegetative swale, porous paving, and landscape infiltration are proposed for reducing highway runoff and improving water quality. The BMPDSS is used to identify and evaluate various alternatives to determine the most cost-effective types and combinations of BMPs that minimize the highway runoff pollution.

关键词： best management practices     decision support system     low impact development     geographic information system     optimization    

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Modification of acidity of Mo-Fe/HZSM-5 zeolite via argon plasma treatment

ZHU Xinli, YU Kailu, CHENG Dangguo, XIA Qing, LIU Changjun, ZHANG Yueping

《化学科学与工程前沿（英文）》 2008年 第2卷 第1期   页码 55-58 doi: 10.1007/s11705-008-0005-4

摘要： The NH-TPD characterization was conducted to confirm that the acidity of Mo-Fe/HZSM-5 zeolite could be selectively modified via the glow discharge plasma treatment. The plasma catalyst treatment could totally change the distribution of aromatic products with higher methane conversion compared to the untreated catalyst. Some polycyclic aromatics such as anthracene, pyrene and phenanthrene were also produced over the plasma treated catalyst, in addition to benzene, toluene and naphthalene, which were normally obtained over the untreated catalyst.

关键词： phenanthrene     Mo-Fe/HZSM-5     conversion     glow discharge     polycyclic    

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Liquefaction prediction using support vector machine model based on cone penetration data

Pijush SAMUI

《结构与土木工程前沿（英文）》 2013年 第7卷 第1期   页码 72-82 doi: 10.1007/s11709-013-0185-y

摘要： A support vector machine (SVM) model has been developed for the prediction of liquefaction susceptibility as a classification problem, which is an imperative task in earthquake engineering. This paper examines the potential of SVM model in prediction of liquefaction using actual field cone penetration test (CPT) data from the 1999 Chi-Chi, Taiwan earthquake. The SVM, a novel learning machine based on statistical theory, uses structural risk minimization (SRM) induction principle to minimize the error. Using cone resistance ( ) and cyclic stress ratio ( ), model has been developed for prediction of liquefaction using SVM. Further an attempt has been made to simplify the model, requiring only two parameters ( and maximum horizontal acceleration ), for prediction of liquefaction. Further, developed SVM model has been applied to different case histories available globally and the results obtained confirm the capability of SVM model. For Chi-Chi earthquake, the model predicts with accuracy of 100%, and in the case of global data, SVM model predicts with accuracy of 89%. The effect of capacity factor ( ) on number of support vector and model accuracy has also been investigated. The study shows that SVM can be used as a practical tool for prediction of liquefaction potential, based on field CPT data.

关键词： earthquake     cone penetration test     liquefaction     support vector machine (SVM)     prediction    

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Current applications of artificial intelligence for intraoperative decision support in surgery

Allison J. Navarrete-Welton, Daniel A. Hashimoto

《医学前沿（英文）》 2020年 第14卷 第4期   页码 369-381 doi: 10.1007/s11684-020-0784-7

摘要： Research into medical artificial intelligence (AI) has made significant advances in recent years, including surgical applications. This scoping review investigated AI-based decision support systems targeted at the intraoperative phase of surgery and found a wide range of technological approaches applied across several surgical specialties. Within the twenty-one ( =21) included papers, three main categories of motivations were identified for developing such technologies: (1) augmenting the information available to surgeons, (2) accelerating intraoperative pathology, and (3) recommending surgical steps. While many of the proposals hold promise for improving patient outcomes, important methodological shortcomings were observed in most of the reviewed papers that made it difficult to assess the clinical significance of the reported performance statistics. Despite limitations, the current state of this field suggests that a number of opportunities exist for future researchers and clinicians to work on AI for surgical decision support with exciting implications for improving surgical care.

关键词： artificial intelligence     decision support     clinical decision support systems     intraoperative     deep learning     computer vision     machine learning     surgery    

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Reliability-based design optimization of offshore wind turbine support structures using RBF surrogate

《结构与土木工程前沿（英文）》   页码 1086-1099 doi: 10.1007/s11709-023-0976-8

摘要： Reliability-based design optimization of offshore wind turbine support structures using RBF surrogate model

关键词： RBF     surrogate model     turbine support structures    

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创造力支持系统的体系结构研究

梁志成,于跃海,仲伟俊

《中国工程科学》 2010年 第12卷 第1期   页码 74-80

摘要：

介绍了创造力支持系统发展历程、创造力与创造性思维，综合研究了各类创造力支持系统，给出了创造力支持系统的构成要素、体系结构，并以构建系统用于电力系统故障分析实例研究，阐述了创造力支持系统对专家思维的支持过程。为创造力支持系统开发实现与应用提供参考。

关键词： 创造力支持系统     体系结构     群体研讨环境     表决链表    

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ENABLING CROP DIVERSIFICATION TO SUPPORT TRANSITIONS TOWARD MORE SUSTAINABLE EUROPEAN AGRIFOOD SYSTEMS

《农业科学与工程前沿（英文）》 2021年 第8卷 第3期   页码 474-480 doi: 10.15302/J-FASE-2021406

摘要：

European cropping systems are often characterized by short rotations or even monocropping, leading to environmental issues such as soil degradation, water eutrophication, and air pollution including greenhouse gas emissions, that contribute to climate change and biodiversity loss. The use of diversification practices (i.e., intercropping, multiple cropping including cover cropping and rotation extension), may help enhance agrobiodiversity and deliver ecosystem services while developing new value chains. Despite its benefits, crop diversification is hindered by various technical, organizational, and institutional barriers along value chains (input industries, farms, trading and processing industries, retailers, and consumers) and within sociotechnical systems (policy, research, education, regulation and advisory). Six EU-funded research projects have joined forces to boost crop diversification by creating the European Crop Diversification Cluster (CDC). This Cluster aggregates research, innovation, commercial and citizen-focused partnerships to identify and remove barriers across the agrifood system and thus enables the uptake of diversification measures by all European value-chain stakeholders. The CDC will produce a typology of barriers, develop tools to accompany actors in their transition, harmonize the use of multicriteria assessment indicators, prepare policy recommendations and pave the way for a long-term network on crop diversification.

 

关键词： crop rotation     lock-in     intercropping     multiple cropping     networking    

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标题 作者 时间 类型 操作

Effects of support acidity on the reaction mechanisms of selective catalytic reduction of NO by CH

Shicheng XU, Junhua LI, Dong YANG, Jiming HAO

期刊论文

Conversion of polyethylene to gasoline: Influence of porosity and acidity of zeolites

期刊论文

Precise regulation of acid pretreatment for red mud SCR catalyst: Targeting on optimizing the acidity

期刊论文

Enhanced CuCl dispersion by regulating acidity of MCM-41 for catalytic oxycarbonylation of ethanol to

Pengzhen CHEN, Shouying HUANG, Jijie ZHANG, Shengping WANG, Xinbin MA

期刊论文

Reductive amination of -hexanol to -hexylamine over Ni–Ce/-AlO catalysts

期刊论文

Vanadium(IV) solvent extraction enhancement in high acidity using di-(2-ethylhexyl)phosphoric acid with

期刊论文

舰船综合保障系统设计

祝 泓,张 平

期刊论文

Socialized care services for the aged population: System construction and support measures

期刊论文

BMP decision support system for evaluating stormwater management alternatives

Mow-Soung CHENG, Jenny X. ZHEN, Leslie SHOEMAKER,

期刊论文

Modification of acidity of Mo-Fe/HZSM-5 zeolite via argon plasma treatment

ZHU Xinli, YU Kailu, CHENG Dangguo, XIA Qing, LIU Changjun, ZHANG Yueping

期刊论文

Liquefaction prediction using support vector machine model based on cone penetration data

Pijush SAMUI

期刊论文

Current applications of artificial intelligence for intraoperative decision support in surgery

Allison J. Navarrete-Welton, Daniel A. Hashimoto

期刊论文

Reliability-based design optimization of offshore wind turbine support structures using RBF surrogate

期刊论文

创造力支持系统的体系结构研究

梁志成,于跃海,仲伟俊

期刊论文

ENABLING CROP DIVERSIFICATION TO SUPPORT TRANSITIONS TOWARD MORE SUSTAINABLE EUROPEAN AGRIFOOD SYSTEMS

期刊论文